Electron transport and precipitation at Mercury during the MESSENGER flybys: Implications for electron-stimulated desorption     

David Schriver  Pavel Trávní?ek  Maha Ashour-Abdalla  Robert L. Richard  Petr Hellinger  James A. Slavin  Brian J. Anderson  Daniel N. Baker  Mehdi Benna  Scott A. Boardsen  Robert E. Gold  George C. Ho  Haje Korth  Stamatios M. Krimigis  William E. McClintock  Jason L. McLain  Thomas M. Orlando  Menelaos Sarantos  Ann L. Sprague  Richard D. Starr 《Planetary and Space Science》2011,59(15):2026-2036

To examine electron transport, energization, and precipitation in Mercury's magnetosphere, a hybrid simulation study has been carried out that follows electron trajectories within the global magnetospheric electric and magnetic field configuration of Mercury. We report analysis for two solar-wind parameter conditions corresponding to the first two MESSENGER Mercury flybys on January 14, 2008, and October 6, 2008, which occurred for similar solar wind speed and density but contrasting interplanetary magnetic field (IMF) directions. During the first flyby the IMF had a northward component, while during the second flyby the IMF was southward. Electron trajectories are traced in the fields of global hybrid simulations for the two flybys. Some solar wind electrons follow complex trajectories at or near where dayside reconnection occurs and enter the magnetosphere at these locations. The entry locations depend on the IMF orientation (north or south). As the electrons move through the entry regions they can be energized as they execute non-adiabatic (demagnetized) motion. Some electrons become magnetically trapped and drift around the planet with energies on the order of 1–10 keV. The highest energy of electrons anywhere in the magnetosphere is about 25 keV, consistent with the absence of high-energy (>35 keV) electrons observed during either MESSENGER flyby. Once within the magnetosphere, a fraction of the electrons precipitates at the planetary surface with fluxes on the order of 10⁹ cm⁻² s⁻¹ and with energies of hundreds of eV. This finding has important implications for the viability of electron-stimulated desorption (ESD) as a mechanism for contributing to the formation of the exosphere and heavy ion cloud around Mercury. From laboratory estimates of ESD ion yields, a calculated ion production rate due to ESD at Mercury is found to be on par with ion sputtering yields.  相似文献   

Anomalous birefringence in andradite–grossular solid solutions: a quantum-mechanical approach     

Valentina Lacivita  Philippe D’Arco  Roberto Orlando  Roberto Dovesi  Alessio Meyer 《Physics and Chemistry of Minerals》2013,40(10):781-788

The static linear optical properties (refractive indices, birefringence and axial angle) of andradite–grossular (Ca₃Fe₂Si₃O₁₂–Ca₃Al₂Si₃O₁₂) solid solutions have been computed at the ab initio quantum-mechanical level through the Coupled Perturbed Kohn–Sham scheme, using an all-electron Gaussian-type basis set. Geometry relaxation after substitution of 1–8 Al for Fe atoms in the primitive cell of andradite yields 23 non-equivalent configurations ranging from cubic to triclinic symmetry. Refractive indices vary quite regularly between the andradite (1.860) and grossular (1.671) end-members; the birefringence δ and the axial angle 2V at intermediate compositions can be as large as 0.02° and 89°, respectively. Comparison with experiments suffers from inhomogeneities and impurities of natural samples; however, semi-quantitative agreement is observed.  相似文献   

Architecture of the deep critical zone in the Río Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) inferred from drilling and ground penetrating radar (GPR)          下载免费PDF全文

Joe Orlando  Xavier Comas  Scott A. Hynek  Heather L. Buss  Susan L. Brantley 《地球表面变化过程与地形》2016,41(13):1826-1840

In the critical zone, surficial bedrock interactions result in the formation of a mantle of chemically‐ and physically‐altered material defined here as regolith. In the watershed of the Río Icacos, an upland river draining the Luquillo Mountains in tropical Puerto Rico, we explored the influence of lithology (quartz diorite versus hornfels‐facies volcaniclastic rock) on weathering. Regolith profiles were studied by drilling boreholes and imaging the subsurface using ground penetrating radar (GPR). Overall, the regolith structure is not laterally continuous but rather is punctuated by zones of deep fractures that host in situ weathering, corestones, and colluvial material. GPR images of these vertical zones show reflectors at 15–20 m depth. Thus, the architecture of the critical zone in the upper Luquillo Mountains is highly dependent on lithology and its influence on fracture development. At the highest elevations where hornfels overlies quartz diorite, positive feedbacks occur when the water table drops so that oxidative weathering of biotite in the more felsic rock creates microfractures and allows deeper infiltration of meteoric waters. Such exposure results in some of the fastest weathering rocks in the world and may contribute to formation of the knickpoint in the Río Icacos watershed. This work represents the first study combining GPR and drilling to look at the structure of the deep critical zone and demonstrates: (1) the importance of combining direct methods (such as drilling) with indirect methods (such as GPR) to understand the architecture of the critical zone in tropical systems; (2) the interplay of the surficial stress regime, lithology and climate in dictating the architecture of weathering. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Variations in the dynamic response of structures founded on piles induced by obliquely incident SV waves     

Cristina Medina  Guillermo M. Álamo  Juan J. Aznárez  Luis A. Padrón  Orlando Maeso 《地震工程与结构动力学》2019,48(7):772-791

Although the seismic actions generally consist of a combination of waves, which propagates with an angle of incidence not necessarily vertical, the common practice when analyzing the dynamic behavior of pile groups is based on the assumption of vertically incident wave fields. The aim of this paper is to analyze how the angle of incidence of SV waves affects the dynamic response of pile foundations and piled structures. A three-dimensional boundary element-finite element coupling formulation is used to compute impedances and kinematic interaction factors corresponding to several configurations of vertical pile groups embedded in an isotropic homogeneous linear viscoelastic half-space. These results, which are provided in ready-to-use dimensionless graphs, are used to determine the effective dynamic properties of an equivalent single-degree-of-freedom oscillator that reproduces, within the range where the peak response occurs, the response of slender and nonslender superstructures through a procedure based on a substructuring model. Results are expressed in terms of effective flexible-base period and damping as well as maximum shear force at the base of the structure. The relevance and main trends observed in the influence of the wavefront angle of incidence on the dynamic behavior of the superstructure are inferred from the presented results. It is found that effective damping is significantly affected by the variations of the wave angle of incidence. Furthermore, it comes out that the vertical incidence is not always the worst-case scenario.  相似文献   

A quantum mechanical study of the perovskite structure type of MgSiO3     

Ph. D'Arco  G. Sandrone  R. Dovesi  R. Orlando  V. R. Saunders 《Physics and Chemistry of Minerals》1993,20(6):407-414

The periodic ab-initio Hartree-Fock Self Consistent Field program CRYSTAL has been used to study the electronic structure and equation of state of MgSiO₃ perovskite. Three space groups were considered: Pm3m (cubic; ideal untilted SiO₆ octahedra), P4/mbm (tetragonal; the octahedra are allowed to deform along and rotate about the crystallographic c cell edge) and Pbnm (orthorhombic; octahedra are allowed to deform along and rotate about the three cell edges). The calculated orthorhombic structure is the most stable, in agreement with experiment. The relative stability of the three structures and the effect of pressure on the SiO₆ octahedra is interpreted in terms of bond population data and is mainly determined by the oxygen-oxygen repulsion.  相似文献   

Corrigendum to “High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin” [J. S. Am. Earth. Sci. Volume 31 (2011) p. 28–44]     

Jaime Orlando Martínez  Eduardo López Ramos 《Journal of South American Earth Sciences》2011,31(2-3):342-343

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Production of amorphous hydrated impure magnesium carbonate through ex situ carbonation     

Andrea Orlando  Matteo Lelli  Luigi Marini 《Applied Geochemistry》2012

The evaluation of the feasibility of ex situ carbonation in landfills utilizing raw natural substances (namely serpentinites as Mg-source and the CO₂-rich fraction of biogas as C-source) was tested through a laboratory procedure comprising three steps. The first step is the acid attack of a serpentinite at 70 °C, by means of HCl 2 M, to get MgCl₂-rich solutions. Attacks of different durations were performed to evaluate the time needed. The second step is the neutralization of the MgCl₂-rich solution by addition of concentrated ammonia. The third (carbonation) step is mixing of the neutralized MgCl₂-rich solution with a solution of ammonium carbonate. This was produced in a landfill by absorption of CO₂ contained in biogas in a solution of ammonia. The neutralization of acid MgCl₂-rich solutions caused the precipitation of ferrihydrite with secondary ammonium carnallite and salammoniac, whereas abundant precipitation of Amorphous Hydrated Impure Magnesium Carbonate (AHIMC), sometimes with minor nesquehonite, occurred in the third step. This solid carbonate acts as a stable CO₂ sink up to 380 °C. The geochemical behavior of some minor elements was also investigated during the experimental processes revealing that Al, Cr and Ni were removed during neutralization (second step), in contrast to Ca which remained in the circumneutral MgCl₂-rich solution and entered into the structure of AHIMC. During the carbonation step, precipitation of artinite, hydromagnesite, lansfordite, magnesite and nesquehonite was thermodynamically impossible as the aqueous phase was undersaturated with respect to these solid phases upon separation of AHIMC.  相似文献   

Surface and groundwater pollution by organochlorine compounds in a typical soybean system from the south Pampa,Argentina   总被引：3，自引：0，他引：3  

Mariana Gonzalez  Karina S. B. Miglioranza  Valeria M. Shimabukuro  Orlando M. Quiroz Londoño  Daniel E. Martinez  Julia E. Aizpún  Víctor J. Moreno 《Environmental Earth Sciences》2012,65(2):481-491

Organochlorine pesticides (OCPs) use has been restricted or forbidden in Argentina since 1998 and technical endosulfan is the last currently used OCPs on the soybean-wheat production. As they persist in soil for several years after application, OCPs constitute a source of environmental pollution. This work aims to assess OCPs contamination of groundwater (Gw) and streamwater (Sw) in the Quequén Grande River watershed from south Argentinean Pampas in relation to the hydrogeological characteristics. OCPs were analyzed in Sw, Gw, surface bottom sediments, soils and borehole cutting sediments (Cs) by gas chromatograph-electron capture detector. Pesticide distribution in Cs was dependent on the characteristic of the non-saturated zone. Leached pesticides over 3 m in Cs showed the pattern: HCHs = endosulfan > chlordanes > DDTs, and from 3 to 6 m heptachlor was the main group as a consequence of the past use of this compound in the area, mainly on potato crops. Endosulfan reaches Gw during application season as well as during flooding events while a retard effect was observed for Sw. Levels of α- and β-isomers were in certain cases above national (7 ng L⁻¹) and international (3 ng L⁻¹) limits for aquatic biota protection. As the endosulfan sulfate metabolite was present in Gw and Sw and due to its high toxicity, it should be considered in the establishment of water quality criteria for human and environmental protection.  相似文献   

The chemical nature of Europa surface material and the relation to a subsurface ocean     

Thomas M. Orlando  Thomas B. McCord 《Icarus》2005,177(2):528-533

The surface composition of Europa is of special interest due to the information it might provide regarding the presence of a subsurface ocean. One source of this information is the infrared reflectance spectrum. Certain surface regions of Europa exhibit distorted H₂O vibrational overtone bands in the 1.5 and 2.0 μm region, as measured by the Galileo mission Near Infrared Mapping Spectrometer (NIMS). These bands are clearly the result of highly concentrated solvated contaminants. However, two interpretations of their identity have been presented. One emphasizes hydrated salt minerals and the other sulfuric acid, although each does not specifically rule out some of the other. It has been pointed out that accurate chemical identification of the surface composition must depend on integrating spectral data with geochemical models, and information on the tenuous atmosphere sputtered from the surface. It is also extremely important to apply detailed chemistry when interpreting the spectral data, including knowledge of mineral dissolution chemistry and the subsequent optical signatures of ion solvation in low-temperature ice. We present studies of flash frozen acid and salt mixtures as Europa surface analogs and demonstrate that solvated protons, metal cations and inorganic anions all influence the spectra and must all, collectively, be considered when assigning Europa spectral features. These laboratory data show best correlation with NIMS Europa spectra for multi-component mixtures of sodium and magnesium bearing sulfate salts mixed with sulfuric acid. The data provide a concentration upper bound of 50-mol% for MgSO₄ and 40-mol% for Na₂SO₄. This newly reported higher sodium and proton content is consistent with low-temperature aqueous differentiation and hydrothermal processing of carbonaceous chondrite-forming materials during the formation and early evolution of Europa.  相似文献   

Seismic response of masonry-infilled steel frames via multi-scale finite-element analyses     

Federico Margiacchi  Luca Salvatori  Maurizio Orlando  Mario De Stefano  Paolo Spinelli 《Bulletin of Earthquake Engineering》2016,14(12):3529-3546

Effects of masonry infills on the seismic vulnerability of steel frames is studied through multi-scale numerical modelling. First, a micro-modelling approach is utilized to define a homogenized masonry material, calibrated on experimental tests, which is used for modelling the nonlinear response of a one-story, single span, masonry-infilled portal under horizontal loads. Based on results of the micro-model, the constitutive behavior of a diagonal strut macro-element equivalent to the infill panel is calibrated. Then, the diagonal strut is used to model infill panels in the macro-scale analysis of a multi-span multi-story infilled moment-resisting (MR) steel frame. The seismic vulnerability of the MR frame is evaluated through a nonlinear static procedure. Numerical analyses highlight that infills may radically modify the seismic response and the failure mechanism of the frame, hence the importance of the infill correct modelling.  相似文献